Solution:The permanent hardness of water is due to the presence of chlorides, nitrates and sulphates of calcium and magnesium in the water. There are various methods of removal of this hardness as simple methods like boiling. lime treatment, Permanent hardness can be removed by Ion Exchange Resin Method, Gan's Permutit Method.
Calgon's Process, etc. But bubbling SO, cannot help in the removal of permanent hardness. Thus, options a, b, and c are correct and option D is incorrect.