Solution:Matching the polymers with their correct structures:
• A-IV: Polypropene → Structure IV
Polypropene (also known as polypropylene) is a polymer formed from the monomer propene (CH₂=CH-CH₃). The structure shows a repeating unit with a -CH₃ (methyl group) attached to the carbon chain, matching structure IV.
• B-III: Polystyrene → Structure III
Polystyrene is made from the monomer styrene (C₆H₅-CH=CH₂). The polymer structure has a phenyl group (C₆H₅) attached to every other carbon in the chain. This corresponds to structure III.
• C-II: Polyvinyl Chloride → Structure II
PVC is derived from vinyl chloride (CH₂=CHCI). The repeating unit shows a -Cl (chlorine) atom attached to the carbon backbone. This matches structure II.
• D-I: Bakelite → Structure I
Bakelite is a thermosetting polymer formed from phenol and formaldehyde. The structure in option I shows a phenol-formaldehyde resin, which is typical of Bakelite. This polymer has aromatic rings with hydroxyl groups connected via methylene bridges. Thus, the correct matching is: A-IV, B-III, С-II, D-I.